Enantioselective synthesis of (+)-α-vetivone through the Michael reaction of chiral imines
Identifieur interne : 001791 ( Main/Exploration ); précédent : 001790; suivant : 001792Enantioselective synthesis of (+)-α-vetivone through the Michael reaction of chiral imines
Auteurs : Gilbert Revial [France] ; Ivan Jabin [France] ; Michel Pfau [France]Source :
- Tetrahedron: Asymmetry [ 0957-4166 ] ; 2001.
Abstract
(+)-α-Vetivone has been synthesised in nine steps. The absolute stereochemistry of the two stereogenic centres is controlled in the same key step involving the stereoselective Michael addition of a chiral imine of 4-isopropylidene-2-methylcyclohexanone to phenyl crotonate.
Url:
DOI: 10.1016/S0957-4166(00)00481-X
Affiliations:
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The absolute stereochemistry of the two stereogenic centres is controlled in the same key step involving the stereoselective Michael addition of a chiral imine of 4-isopropylidene-2-methylcyclohexanone to phenyl crotonate.</div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Haute-Normandie</li><li>Région Normandie</li><li>Île-de-France</li></region><settlement><li>Le Havre</li><li>Paris</li></settlement><orgName><li>Université du Havre</li></orgName></list><tree><country name="France"><region name="Île-de-France"><name sortKey="Revial, Gilbert" sort="Revial, Gilbert" uniqKey="Revial G" first="Gilbert" last="Revial">Gilbert Revial</name></region><name sortKey="Jabin, Ivan" sort="Jabin, Ivan" uniqKey="Jabin I" first="Ivan" last="Jabin">Ivan Jabin</name><name sortKey="Pfau, Michel" sort="Pfau, Michel" uniqKey="Pfau M" first="Michel" last="Pfau">Michel Pfau</name><name sortKey="Revial, Gilbert" sort="Revial, Gilbert" uniqKey="Revial G" first="Gilbert" last="Revial">Gilbert Revial</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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